Alexander T Radosevich

Publication Activity (10 Years)

Years Active: 2017-2024
Publications (10 Years): 35

Top Topics

Molecular Docking

Electron Transfer

Transition Metal

Top Venues

Journal of the American Chemical Society

Angewandte Chemie (International ed. in English)

Chemical science

Inorganic chemistry

This page only lists publications with an associated author ORCID identifier.

Publications

Shicheng Hu, Alexander T Radosevich
Electrophilic C(sp 2 )-H Cyanation with Inorganic Cyanate (OCN - ) by P III /P V =O-Catalyzed Phase Transfer Activation. Angewandte Chemie (International ed. in English) (2024)
Hye Won Moon, Marissa N Lavagnino, Soohyun Lim, Maximilian D Palkowitz, Michael D Mandler, Gregory L Beutner, Myles J Drance, Jeffrey M Lipshultz, Paul M Scola, Alexander T Radosevich
Deoxyfluorination of 1°, 2°, and 3° Alcohols by Nonbasic O-H Activation and Lewis Acid-Catalyzed Fluoride Shuttling. Journal of the American Chemical Society (2023)
Daniel Roth, Alexander T Radosevich, Lutz Greb
Reversible Oxidative Addition of Nonactivated C-H Bonds to Structurally Constrained Phosphenium Ions. Journal of the American Chemical Society (2023)
Seung Youn Hong, Alexander T Radosevich
Chemoselective Primary Amination of Aryl Boronic Acids by P III /P V ═O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO. Journal of the American Chemical Society 144 (20) (2022)
Myles J Drance, Akira Tanushi, Alexander T Radosevich
Two-Site O-H Addition to an Iridium Complex Featuring a Nonspectator Tricoordinate Phosphorus Ligand. Journal of the American Chemical Society 144 (44) (2022)
Gen Li, Yuzuru Kanda, Seung Youn Hong, Alexander T Radosevich
Enabling Reductive C-N Cross-Coupling of Nitroalkanes and Boronic Acids by Steric Design of P(III)/P(V)═O Catalysts. Journal of the American Chemical Society 144 (18) (2022)
Gen Li, Marissa N Lavagnino, Siraj Z Ali, Shicheng Hu, Alexander T Radosevich
Tandem C/N-Difunctionalization of Nitroarenes: Reductive Amination and Annulation by a Ring Expansion/Contraction Sequence. Journal of the American Chemical Society 145 (1) (2022)
Gen Li, Marissa N Lavagnino, Siraj Z Ali, Shicheng Hu, Alexander T Radosevich
Tandem C/N-Difunctionalization of Nitroarenes: Reductive Amination and Annulation by a Ring Expansion/Contraction Sequence. Journal of the American Chemical Society 145 (1) (2022)
Gen Li, Marissa N Lavagnino, Siraj Z Ali, Shicheng Hu, Alexander T Radosevich
Tandem C/N-Difunctionalization of Nitroarenes: Reductive Amination and Annulation by a Ring Expansion/Contraction Sequence. Journal of the American Chemical Society 145 (1) (2022)
Quinton J Bruch, Akira Tanushi, Peter Müller, Alexander T Radosevich
Metal-Ligand Role Reversal: Hydride-Transfer Catalysis by a Functional Phosphorus Ligand with a Spectator Metal. Journal of the American Chemical Society 144 (47) (2022)
Gen Li, Marissa N Lavagnino, Siraj Z Ali, Shicheng Hu, Alexander T Radosevich
Tandem C/N-Difunctionalization of Nitroarenes: Reductive Amination and Annulation by a Ring Expansion/Contraction Sequence. Journal of the American Chemical Society 145 (1) (2022)
Gen Li, Marissa N Lavagnino, Siraj Z Ali, Shicheng Hu, Alexander T Radosevich
Tandem C/N-Difunctionalization of Nitroarenes: Reductive Amination and Annulation by a Ring Expansion/Contraction Sequence. Journal of the American Chemical Society (2022)
Gen Li, Marissa N Lavagnino, Siraj Z Ali, Shicheng Hu, Alexander T Radosevich
Tandem C/N-Difunctionalization of Nitroarenes: Reductive Amination and Annulation by a Ring Expansion/Contraction Sequence. Journal of the American Chemical Society 145 (1) (2022)
Jeffrey M Lipshultz, Alexander T Radosevich
Uniting Amide Synthesis and Activation by PIII/PV-Catalyzed Serial Condensation: Three-Component Assembly of 2-Amidopyridines. Journal of the American Chemical Society 143 (36) (2021)
Jeffrey M Lipshultz, Gen Li, Alexander T Radosevich
Main Group Redox Catalysis of Organopnictogens: Vertical Periodic Trends and Emerging Opportunities in Group 15. Journal of the American Chemical Society 143 (4) (2021)
Gen Li, Steven P Miller, Alexander T Radosevich
PIII/PV═O-Catalyzed Intermolecular N-N Bond Formation: Cross-Selective Reductive Coupling of Nitroarenes and Anilines. Journal of the American Chemical Society 143 (36) (2021)
Trevor V Nykaza, Gen Li, Junyu Yang, Michael R Luzung, Alexander T Radosevich
PIII /PV =O Catalyzed Cascade Synthesis of N-Functionalized Azaheterocycles. Angewandte Chemie (International ed. in English) 59 (11) (2020)
Jeffrey M Lipshultz, Yue Fu, Peng Liu, Alexander T Radosevich
Organophosphorus-catalyzed relay oxidation of H-Bpin: electrophilic C-H borylation of heteroarenes. Chemical science 12 (3) (2020)
Soohyun Lim, Alexander T Radosevich
Round-Trip Oxidative Addition, Ligand Metathesis, and Reductive Elimination in a PIII/PV Synthetic Cycle. Journal of the American Chemical Society 142 (38) (2020)
Gen Li, Trevor V Nykaza, Julian C Cooper, Antonio Ramirez, Michael R Luzung, Alexander T Radosevich
An Improved PIII/PV═O-Catalyzed Reductive C-N Coupling of Nitroaromatics and Boronic Acids by Mechanistic Differentiation of Rate- and Product-Determining Steps. Journal of the American Chemical Society 142 (14) (2020)
Gen Li, Ziyang Qin, Alexander T Radosevich
P(III)/P(V)-Catalyzed Methylamination of Arylboronic Acids and Esters: Reductive C-N Coupling with Nitromethane as a Methylamine Surrogate. Journal of the American Chemical Society 142 (38) (2020)
R Morris Bullock, Jingguang G Chen, Soumen Ghosh, Paul J Chirik, Omar K Farha, Christopher H Hendon, Christopher W Jones, John A Keith, Jerzy Klosin, Shelley D Minteer, Robert H Morris, Alexander T Radosevich, Thomas B Rauchfuss, Neil A Strotman, Aleksandra Vojvodic, Thomas R Ward, Jenny Y Yang, Yogesh Surendranath
Using nature's blueprint to expand catalysis with Earth-abundant metals. Science (New York, N.Y.) 369 (6505) (2020)
Seung Jun Hwang, Akira Tanushi, Alexander T Radosevich
Enthalpy-Controlled Insertion of a "Nonspectator" Tricoordinate Phosphorus Ligand into Group 10 Transition Metal-Carbon Bonds. Journal of the American Chemical Society 142 (51) (2020)
Kyounghoon Lee, Anastasia V Blake, Akira Tanushi, Sean M McCarthy, Daniel Kim, Sydney M Loria, Courtney M Donahue, Kyle D Spielvogel, Jason M Keith, Scott R Daly, Alexander T Radosevich
Validating the Biphilic Hypothesis of Nontrigonal Phosphorus(III) Compounds. Angewandte Chemie (International ed. in English) 58 (21) (2019)
Gregory T Cleveland, Alexander T Radosevich
A Nontrigonal Tricoordinate Phosphorus Ligand Exhibiting Reversible "Nonspectator" L/X-Switching. Angewandte Chemie (International ed. in English) 58 (42) (2019)
J Connor Gilhula, Alexander T Radosevich
Tetragonal phosphorus(v) cations as tunable and robust catalytic Lewis acids. Chemical science 10 (30) (2019)
Avipsa Ghosh, Morgan Lecomte, Shin-Ho Kim-Lee, Alexander T Radosevich
Organophosphorus-Catalyzed Deoxygenation of Sulfonyl Chlorides: Electrophilic (Fluoroalkyl)sulfenylation by PIII /PV =O Redox Cycling. Angewandte Chemie (International ed. in English) 58 (9) (2019)
Morgan Lecomte, Jeffrey M Lipshultz, Shin-Ho Kim-Lee, Gen Li, Alexander T Radosevich
Driving Recursive Dehydration by PIII/PV Catalysis: Annulation of Amines and Carboxylic Acids by Sequential C-N and C-C Bond Formation. Journal of the American Chemical Society 141 (32) (2019)
Trevor V Nykaza, Julian C Cooper, Gen Li, Nolwenn Mahieu, Antonio Ramirez, Michael R Luzung, Alexander T Radosevich
Intermolecular Reductive C-N Cross Coupling of Nitroarenes and Boronic Acids by PIII/PV═O Catalysis. Journal of the American Chemical Society 140 (45) (2018)
Trevor V Nykaza, Antonio Ramirez, Tyler S Harrison, Michael R Luzung, Alexander T Radosevich
Biphilic Organophosphorus-Catalyzed Intramolecular Csp2-H Amination: Evidence for a Nitrenoid in Catalytic Cadogan Cyclizations. Journal of the American Chemical Society 140 (8) (2018)
Yi-Chun Lin, James C Gilhula, Alexander T Radosevich
Nontrigonal constraint enhances 1,2-addition reactivity of phosphazenes. Chemical science 9 (18) (2018)
Akira Tanushi, Alexander T Radosevich
Insertion of a Nontrigonal Phosphorus Ligand into a Transition Metal-Hydride: Direct Access to a Metallohydrophosphorane. Journal of the American Chemical Society 140 (26) (2018)
Trevor V Nykaza, Tyler S Harrison, Avipsa Ghosh, Rachel A Putnik, Alexander T Radosevich
A Biphilic Phosphetane Catalyzes N-N Bond-Forming Cadogan Heterocyclization via PIII/PV═O Redox Cycling. Journal of the American Chemical Society 139 (20) (2017)
Yi-Chun Lin, Emmanuel Hatzakis, Sean M McCarthy, Kyle D Reichl, Ting-Yi Lai, Hemant P Yennawar, Alexander T Radosevich
P-N Cooperative Borane Activation and Catalytic Hydroboration by a Distorted Phosphorous Triamide Platform. Journal of the American Chemical Society 139 (16) (2017)
Allen J Pistner, Hye Won Moon, Alexey Silakov, Hemant P Yennawar, Alexander T Radosevich
Stable Open-Shell Phosphorane Based on a Redox-Active Amidodiphenoxide Scaffold. Inorganic chemistry 56 (15) (2017)