The Compliance of the Upper Critical Field in Magic-Angle Multilayer Graphene with the Pauli Limit.

The Pauli limiting field represents a fundamental magnetic field at which the superconducting state collapses due to the spin-paramagnetic Cooper pair-breaking effect. Cao et al. (Nature 2021, 595, 526) reported that the magic-angle twisted trilayer graphene (MATNG, N = 3) exhibits the upper critical field which exceeds the Pauli limiting field by two to three times. This observation was interpreted as a violation of the Pauli-limiting field in MAT3G. Similar conclusions were recently reported by the same research group in MATNG (N = 4, 5) superlattices (Park, J.M. et al. Nat. Mater.2022, 21, 877). Here, we point out that Cao et al. (Nature 2021, 595, 526) calculated the Pauli limiting field by the use of reduced form (to the weak-coupling limit) of full equation of the theory of the electron−phonon-mediated superconductivity. Considering that in the same paper, Cao et al. (Nature 2021, 595, 526) reported that MATNGs are strong coupled superconductors, we calculate the Pauli limiting field for a strong coupled case and show that the observed upper critical fields in MATNGs comply with the Pauli limit. This implies that there is no violation of the Pauli limiting field in the Moiré multilayer graphene superlattices.