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Crystal structure and Hirshfeld surface analysis of 6,6'-((1 E ,1' E )-{[1,4-phenyl-enebis(methyl-ene)]bis(aza-nylyl-idene)}bis-(methane-ylyl-idene))bis-(2-meth-oxy-phenol).

Sevgi KansızSemanur YesilbagNecmi DegeEiad SaifErbil Agar
Published in: Acta crystallographica. Section E, Crystallographic communications (2022)
The Schiff base compound, C 24 H 24 N 2 O 4 , was synthesized by the inter-action of 2-hy-droxy-3-meth-oxy benzaldehyde and 1,4-benzene dimethanamine in ethanol, and crystallizes in the monoclinic space group P 2 1 / n with Z ' = 0.5. The mol-ecule is not planar, the 1,4-di-ethyl-benzene and the phenol rings are twisted with respect to each other, making a dihedral angle of 74.27 (5)°. The mol-ecular structure is stabilized by an O-H⋯N hydrogen bond, forming an S (6) ring motif. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, resulting in the formation of sheets parallel to the bc plane. A Hirshfeld surface analysis was undertaken to investigate the various inter-molecular contacts controlling the supra-molecular topology, suggesting the H⋯O (18%) contacts to be the most significant inter-actions, whereas the H⋯H (50.5%) and C⋯H (24.3%) inter-actions are less significant.
Keyphrases
  • mass spectrometry
  • crystal structure
  • ionic liquid
  • high resolution
  • escherichia coli