Atomically Dispersed Electron Traps in Cu Doped BiOBr Boosting CO 2 Reduction to Methanol by Pure H 2 O.
Ke WangMing ChengFanjie XiaNing CaoFanxing ZhangWenkang NiXuanyu YueKeping YanYi HeYao ShiWenxin DaiPengfei XiePublished in: Small (Weinheim an der Bergstrasse, Germany) (2023)
Overall photocatalytic conversion of CO 2 and pure H 2 O driven by solar irradiation into methanol provides a sustainable approach for extraterrestrial synthesis. However, few photocatalysts exhibit efficient production of CH 3 OH. Here, BiOBr nanosheets supporting atomic Cu catalysts for CO 2 reduction are reported. The investigation of charge dynamics demonstrates a strong built-in electric field established by isolated Cu sites as electron traps to facilitate charge transfer and stabilize charge carriers. As result, the catalysts exhibit a substantially high catalytic performance with methanol productivity of 627.66 µmol g catal -1 h -1 and selectivity of ≈90% with an apparent quantum efficiency of 12.23%. Mechanism studies reveal that the high selectivity of methanol can be ascribed to energy-favorable hydrogenation of *CO intermediate giving rise to *CHO. The unfavorable adsorption on Cu 1 @BiOBr prevents methanol from being oxidized by photogenerated holes. This work highlights the great potential of single-atom photocatalysts in chemical transformation and energy storage reactions.
Keyphrases
- visible light
- carbon dioxide
- metal organic framework
- aqueous solution
- solar cells
- highly efficient
- molecular dynamics
- climate change
- genome wide
- mouse model
- computed tomography
- risk assessment
- electron microscopy
- magnetic resonance imaging
- room temperature
- quantum dots
- radiation therapy
- transition metal
- radiation induced
- ionic liquid
- crystal structure
- diffusion weighted imaging