A focus on applying 63/65 Cu solid-state NMR spectroscopy to characterize Cu MOFs.

Metal-organic frameworks (MOFs) are a class of hybrid organic and inorganic porous materials that have shown prospects in applications ranging from gas storage, separation, catalysis, etc. Although they can be studied using various characterization techniques, these methods often do not provide local structural details that help explain their functionality. Zhang et al. (W. Zhang, B. E. G. Lucier, V. V. Terskikh, S. Chen and Y. Huang, Chem. Sci. , 2024, https://doi.org/10.1039/D4SC00782D) have recently exploited 63/65 Cu solid-state NMR spectroscopy (for the first time) and DFT calculations to elucidate the structures of Cu(i) centers in MOFs. While there are still many challenges in overcoming issues in resolution and sensitivity, this work lays the foundation for further development of solid-state NMR technology in characterizing copper in MOFs or other amorphous solids.