The purpose of the study was to examine the acoustic features of sibilant fricatives and affricates produced by prelingually deafened Mandarin-speaking children with cochlear implants (CIs) in comparison to their age-matched normal-hearing (NH) peers. The speakers included 21 children with NH aged between 3.25 and 10 years old and 35 children with CIs aged between 3.77 and 15 years old who were assigned into chronological-age-matched and hearing-age-matched subgroups. All speakers were recorded producing Mandarin words containing nine sibilant fricatives and affricates (/s, ɕ, ʂ, ts, tsʰ, tɕ, tɕʰ, tʂ, tʂʰ/) located at the word-initial position. Acoustic analysis was conducted to examine consonant duration, normalized amplitude, rise time, and spectral peak. The results revealed that the CI children, regardless of whether chronological-age-matched or hearing-age-matched, approximated the NH peers in the features of duration, amplitude, and rise time. However, the spectral peaks of the alveolar and alveolopalatal sounds in the CI children were significantly lower than in the NH children. The lower spectral peaks of the alveolar and alveolopalatal sounds resulted in less distinctive place contrast with the retroflex sounds in the CI children than in the NH peers, which might partially account for the lower intelligibility of high-frequency consonants in children with CIs.