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Visible-light-induced C sp 3 -H functionalization of glycine derivatives by cerium catalysis.

Junqiang LeiYanjie YeYansong HuXu MengZhao LiuJiyu LiuKuan ChenZhengze ZhangYuan Zhang
Published in: Chemical communications (Cambridge, England) (2023)
A Ce(III)-catalyzed, visible-light-induced aerobic oxidative dehydrogenative coupling/aromatization reaction between glycine derivatives and alkenes has been developed, which provides an efficient approach for the synthesis of quinoline derivatives and post-modification of oligopeptides containing glycine residues under mild conditions without the need for external photosensitizers.
Keyphrases
  • visible light
  • structure activity relationship
  • room temperature
  • high glucose
  • diabetic rats
  • molecular docking
  • oxidative stress
  • endothelial cells
  • oxide nanoparticles
  • molecular dynamics simulations
  • energy transfer