Synthesis of 2-Indolyl C -Glycoside Neopetrosins A and C and Congeners via Ni-Catalyzed Photoreductive Cross-Coupling.
Yan XiaYingjie WangZhaolun ZhangTayyab GulzarYuqi LinJing WangDapeng ZhuBiao YuPublished in: Organic letters (2023)
The synthesis of neopetrosins A and C, two 2-indolyl C -α-d-mannopyranosides, and their congeners has been realized via a direct Ni/photoredox-catalyzed reductive coupling of 3-methoxycarbonyl-2-iodo-1 H -indoles with pyranosyl bromides.