Borylated cyclobutanes via thermal [2 + 2]-cycloaddition.

Kateryna PrysiazhniukOleksandr PolishchukStanislav ShulhaKyrylo GudzikevychOleksandr P DatsenkoVladimir Kubyshkin Pavel K Mykhailiuk

Published in: Chemical science (2024)

A one-step approach to borylated cyclobutanes from amides of carboxylic acids and vinyl boronates is elaborated. The reaction proceeds via the thermal [2 + 2]-cycloaddition of in situ -generated keteniminium salts.

Keyphrases

ionic liquid