Electrophilic Methylation of Decaborane(14): Selective Synthesis of Tetramethylated and Heptamethylated Decaboranes and Their Conjugated Bases.
Josef HolubAleš RůŽičkaZdeňka RůžičkováJindřich FanfrlíkDrahomír HnykBohumil ŠtíbrPublished in: Inorganic chemistry (2020)
The paper reports specific syntheses of methylated decaborane(14), nido-B10H14 (1), derivatives. The reaction of 1 with an excess of neat MeI and AlCl3 yields 1,2,3,4-Me4-nido-B10H10 (2) essentially quantitatively when performed at room temperature. Heating the same mixture to 120 °C provides 1-I-2,3,4,5,7,8,10-Me7-nido-B10H6 (3a). The formation of analogous 1-CF3SO2O-2,3,4,5,7,8,10-Me7-nido-B10H6 (3b) is achieved by heating 1 or 2 with an excess of MeSO3CF3 in the presence of a catalytic amount of HOSO2CF3 to 120 °C. Compounds 2 and 3 can be deprotonated to yield the corresponding anions [1,2,3,4-Me4-nido-B10H9]- (2-), [1-I-2,3,4,5,7,8,10-Me7-nido-B10H5]- (3a-), and [1-CF3SO2O-2,3,4,5,7,8,10-Me7-nido-B10H5]- (3b-). The structure of all the compounds isolated has been unambiguously confirmed by multinuclear (11B and 1H) NMR measurements, and the structures of 2-, 3a, 3a-, and 3b have been established by X-ray diffraction analyses. The very high volatility of 2 has made it impossible to apply X-ray diffraction in this case; therefore, its structure has been derived computationally using the ab initio/GIAO/NMR tool. DFT-based computational protocols have also outlined the reason why it is impossible to obtain an octamethyl derivative of 1 experimentally.