Statistical Optimisation of Chemical Stability of Hybrid Microwave-Sintered Alumina Ceramics in Nitric Acid.

The goal of this research is the statistical optimisation of the chemical stability of hybrid microwave-sintered alumina ceramics in nitric acid. The chemical stability of ceramic materials in corrosive media depends on many parameters, such as the chemical and phase composition of the ceramics, the properties of the aggressive medium (concentration, temperature, and pressure), and the exposure time. Therefore, the chemical stability of alumina ceramics in different aqueous nitric acid solution concentrations (0.50 mol dm -3 , 1.25 mol dm -3 , and 2.00 mol dm -3 ), different exposure times (up to 10 days), as well as different temperatures (25, 40, and 55 °C), was investigated, modelled, and optimised. The chemical stability of high purity alumina ceramics (99.8345 wt.% of Al 2 O 3 ) was determined by measuring the amount of eluted ions (Al 3+ , Ca 2+ , Fe 3+ , Mg 2+ , Na + , and Si 4+ ) obtained by inductively coupled plasma atomic emission spectrometry. The changes in the density of alumina ceramics during the chemical stability monitoring were also determined. The Box-Behnken approach was employed to reach the optimum conditions for obtaining the highest possible chemical stability of alumina at a given temperature range, exposure time, and molar concentration of nitric acid. It was found that an increase in exposure time, temperature, and nitric acid concentration led to an increase in the elution of ions from hybrid microwave-sintered alumina. Higher amounts of eluted ions, Al 3+ (14.805 µg cm -2 ), Ca 2+ (7.079 µg cm -2 ), Fe 3+ (0.361 µg cm -2 ), Mg 2+ (3.654 µg cm -2 ), and Na + ions (13.261 µg cm -2 ), were obtained at 55 °C in the 2 mol dm - 3 nitric acid. The amount of eluted Si 4+ ions is below the detection limit of inductively coupled plasma atomic emission spectrometry. The change in the alumina ceramic density during the corrosion test was negligible.