Rare-Earth (RE = Y, Gd, Tb, Dy, Ho, and Er) Chains Bridged with a Triplet Biradical and Magnetic Hysteresis Recorded for RE = Tb.

Complex formation of 5- tert -butyl-1,3-phenylene bis( tert -butyl nitroxide) and rare-earth (RE) metal ions gave a linear chain where each nitroxide O atom is directly bonded to the RE ion. The bridge was proven to be a ground triplet molecule in the complexes. A hysteresis loop was recorded below 2.8 K as a single-chain magnet for the RE = Tb derivative.