Phosphine/Sulfoxide-Supported Carbon(0) Complex.
Mariana Lozano GonzálezLaura BousquetSophie HameuryCecilio Alvarez ToledanoNathalie Saffon-MerceronVicenç BranchadellEddy MaertenAntoine BaceiredoPublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2018)
A new carbon(0) complex 2 with two different L ligands, a phosphine and a sulfoxide, was synthesized and fully characterized. This new type of carbone exhibits excellent coordination ability, in contrast to the related phosphine/sulfide-supported carbon(0) complexes. Several organometallic complexes were isolated and, of special interest, the νav (CO) value of RhI -dicarbonyl complex indicates that 2 has a donor capability superior to classical NHCs.