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Hybrid Catalysts for Enantioselective Photo-Phosphoric Acid Catalysis.

Alessa B RolkaNataliya ArchipowaRoger J KuttaBurkhard KönigF Dean Toste
Published in: The Journal of organic chemistry (2023)
The syntheses of two novel, organic, and chiral photocatalysts are presented. By combining donor-acceptor cyanoarene-based photocatalysts with a chiral phosphoric acid, bifunctional catalysts have been designed. In preliminary proof-of-concept reactions, their use in both enantioselective energy transfer and photoredox catalysis is demonstrated.
Keyphrases
  • visible light
  • energy transfer
  • highly efficient
  • quantum dots
  • metal organic framework
  • ionic liquid
  • capillary electrophoresis
  • transition metal
  • water soluble