Emerging Two-Dimensional Inorganic Molecular Crystals: The Concept and Beyond.

The concept of two-dimensional (2D) inorganic molecular crystals (IMCs) was first introduced by Zhai and coauthors in 2019. In contrast to the layered structures of graphene-like 2D materials, 2D IMCs consist of tiny inorganic molecules bonded together through all-around van der Waals (vdW) interactions. Their structural peculiarities lead to some special behaviors and appealing properties in their synthesis and applications. In this Perspective, we first introduce the concept of 2D IMCs and present the very first synthesis of 2D IMCs using a surface-passivated growth approach. The special intermolecular effects between the inorganic molecules are also summarized. In addition, because of its molecular structure, a vdW film of IMCs can be facilely fabricated, which exhibits appealing potential in integrated 2D devices. More importantly, we give a general outlook for the further development of 2D IMCs with the goal of attracting more attention to this emerging research frontier.