Hydrogen-bonded nickel(I) complexes.

Jessica R WilsonMatthias ZellerNathaniel K Szymczak

Published in: Chemical communications (Cambridge, England) (2021)

A series of nickel(ii) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the nickel(i) state provided access to an unusual nickel(i) fluoride complex stabilized by H-bonds, enabling structural and spectroscopic characterization.

Keyphrases

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