Pyridyl-Directed Cp*Rh(III)-Catalyzed B(3)-H Acyloxylation of o-Carborane.
Chun-Xiao LiHao-Yun ZhangTsz-Yung WongHou-Ji CaoHong YanChang-Sheng LuPublished in: Organic letters (2017)
An efficient pyridyl-directed Rh(III)-catalyzed o-carborane B(3)-H acyloxylation is reported. The B(3)-H bond is the most electron-deficient vertex on o-carborane whose functionalization is challenging. The combination of Cu(OH)2 and diverse carboxylic acids provides low cost and abundant acyloxyl sources which could lead to moderate to excellent yields.