Molecular electronic spin qubits from a spin-frustrated trinuclear copper complex.
Benjamin KintzelMichael BöhmeJunjie LiuAnja BurkhardtJakub MrozekAxel BuchholzArzhang ArdavanWinfried PlassPublished in: Chemical communications (Cambridge, England) (2018)
The trinuclear copper(ii) complex [Cu3(saltag)(py)6]ClO4 (H5saltag = tris(2-hydroxybenzylidene)triaminoguanidine) was synthesized and characterized by experimental as well as theoretical methods. This complex exhibits a strong antiferromagnetic coupling (J = -298 cm-1) between the copper(ii) ions, mediated by the N-N diazine bridges of the tritopic ligand, leading to a spin-frustrated system. This compound shows a T2 coherence time of 340 ns in frozen pyridine solution, which extends to 591 ns by changing the solvent to pyridine-d5. Hence, the presented compound is a promising candidate as a building block for molecular spintronics.