Fast, Noncontact, Wafer-Scale, Atomic Layer Resolved Imaging of Two-Dimensional Materials by Ellipsometric Contrast Micrography.
Philipp Braeuninger-WeimerSebastian FunkeRuizhi WangPeter ThiesenDaniel TascheWolfgang ViölStephan HofmannPublished in: ACS nano (2018)
Adequate characterization and quality control of atomically thin layered materials (2DM) has become a serious challenge particularly given the rapid advancements in their large area manufacturing and numerous emerging industrial applications with different substrate requirements. Here, we focus on ellipsometric contrast micrography (ECM), a fast intensity mode within spectroscopic imaging ellipsometry, and show that it can be effectively used for noncontact, large area characterization of 2DM to map coverage, layer number, defects and contamination. We demonstrate atomic layer resolved, quantitative mapping of chemical vapor deposited graphene layers on Si/SiO2-wafers, but also on rough Cu catalyst foils, highlighting that ECM is applicable to all application relevant substrates. We discuss the optimization of ECM parameters for high throughput characterization. While the lateral resolution can be less than 1 μm, we particularly explore fast scanning and demonstrate imaging of a 4″ graphene wafer in 47 min at 10 μm lateral resolution, i.e., an imaging speed of 1.7 cm2/min. Furthermore, we show ECM of monolayer hexagonal BN (h-BN) and of h-BN/graphene bilayers, highlighting that ECM is applicable to a wide range of 2D layered structures that have previously been very challenging to characterize and thereby fills an important gap in 2DM metrology.
Keyphrases
- high resolution
- room temperature
- high throughput
- extracellular matrix
- quality control
- magnetic resonance
- type diabetes
- skeletal muscle
- minimally invasive
- mass spectrometry
- molecular docking
- healthcare
- highly efficient
- reduced graphene oxide
- metabolic syndrome
- magnetic resonance imaging
- wastewater treatment
- single molecule
- computed tomography
- glycemic control
- adipose tissue
- quantum dots
- electron microscopy
- ion batteries