WO3-Based Slippery Liquid-Infused Porous Surfaces with Long-Term Stability.

Slippery liquid-infused porous surfaces (SLIPS) inspired by Nepenthes pitcher plants exhibit excellent hydrophobicity, antifouling and anti-icing properties, and long-term durability under pressure and temperature. SLIPS have potential applications including in biomedical devices, self-cleaning structures, and water-resistant coatings. A big challenge posed by SLIPS is the durability of the lubricant in the porous layer. Herein, uniform tungsten oxide nanofiber networks were synthesized on the surface of stainless steel through a simple one-step hydrothermal method. WO3 nanofiber networks on stainless steels were chemically modified, filled with a lubricant, and prepared as SLIPS with excellent liquid repellency and good anti-biofouling properties. The relationship of the nanostructures and the slippery properties of the obtained WO3-based SLIPS have been investigated in detail in this work. The liquid retention and long-term stability of the SLIPS were characterized using high shear force and water flow impact. We found that the long-term durability of the SLIPS is strongly related to the diameters and the Brunauer-Emmett-Teller surface areas of the WO3 nanostructures. The durability of the SLIPS is better when the diameter of the WO3 nanostructures is smaller. The WO3-based SLIPS prepared in this work exhibit outstanding slippery property, anti-biofouling, and long-term stability under extreme conditions such as high shear rate and water washing and thus may have potential application for surface modification of medical devices in the future.