Comparison of Conventional and Nonconventional Hydrogen Bond Donors in Au - Complexes.

Although gold has become a well-known nonconventional hydrogen bond acceptor, interactions with nonconventional hydrogen bond donors have been largely overlooked. In order to provide a better understanding of these interactions, two conventional hydrogen bonding molecules (3-hydroxytetrahydrofuran and alaninol) and two nonconventional hydrogen bonding molecules (fenchone and menthone) were selected to form gas-phase complexes with Au - . The Au - [M] complexes were investigated using anion photoelectron spectroscopy and density functional theory. Au - [fenchone], Au - [menthone], Au - [3-hydroxyTHF], and Au - [alaninol] were found to have vertical detachment energies of 2.71 ± 0.05, 2.76 ± 0.05, 3.01 ± 0.03, and 3.02 ± 0.03 eV, respectively, which agree well with theory. The photoelectron spectra of the complexes resemble the spectrum of Au - but are blueshifted due to the electron transfer from Au - to M. With density functional theory, natural bond orbital analysis, and atoms-in-molecules analysis, we were able to extend our comparison of conventional and nonconventional hydrogen bonding to include geometric and electronic similarities. In Au - [3-hydroxyTHF] and Au - [alaninol], the hydrogen bonding comprised of Au - ···HO as a strong, primary hydrogen bond, with secondary stabilization by weaker Au - ···HN or Au - ···HC hydrogen bonds. Interestingly, the Au - ···HC bonds in Au - [fenchone] and Au - [menthone] can be characterized as hydrogen bonds, despite their classification as nonconventional hydrogen bond donors.