Zintl Ions and Phases Promote the Catalytic Hydrophosphination of Alkynes, Alkenes, and Imines.

Although Zintl ions and phases have been known for more than a century, their application as tools to build organic molecules is underdeveloped. Here, a range of Zintl ions and phases were surveyed in the hydrophosphination of alkynes, alkenes, and imines with diphenylphosphine to afford useful organophosphine products. Further investigations with diphenylphosphine in the absence of the unsaturated organic substrates revealed the formation of the diphenylphosphide anion, allowing for the conclusion that the role of the Zintl species is as an initiator in these transformations.