The Interphase Gas-Solid Synthesis of Ammonium Alginate-The Comparison of Two Synthesis Methods and the Effect of Low Molecular Weight Electrolyte Presence.

This paper presents a method for the synthesis of ammonium alginate by interphase gas-solid reaction. It was confirmed by FTIR ATR spectroscopy analysis that a full substitution of acid groups by ammonium groups on the surface of powdered alginic acid was performed. Comparative studies on the properties of ammonium alginate solutions obtained by interphase reaction with those prepared by the classical method of dissolving alginic acid in an ammonia solution showed that the rheological properties of the solutions from these two derivatives do not differ significantly. Moreover, it was shown that aqueous solutions of ammonium alginate are more stable over time than solutions of sodium alginate. It was confirmed that ammonium alginate and sodium alginate are typical polyelectrolytes, as the addition of a low molecular weight electrolyte to their solutions resulted in a decrease in viscosity.