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Degradation of Methylene Blue Dye in the Presence of Visible Light Using SiO₂@α-Fe₂O₃ Nanocomposites Deposited on SnS₂ Flowers.

Sridharan BaluKasimayan UmaGuan-Ting PanThomas Chung Kuang YangSayee Kannan Ramaraj
Published in: Materials (Basel, Switzerland) (2018)
Semiconductor materials have been shown to have good photocatalytic behavior and can be utilized for the photodegradation of organic pollutants. In this work, three-dimensional flower-like SnS₂ (tin sulfide) was synthesized by a facile hydrothermal method. Core-shell structured SiO₂@α-Fe₂O₃ nanocomposites were then deposited on the top of the SnS₂ flowers. The as-synthesized nanocomposites were characterized by X-ray diffraction (XRD), Raman spectroscopy, field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV⁻Vis Spectroscopy, Brunauer⁻Emmett⁻Teller (BET) surface area analysis, and photoluminescence (PL) spectroscopy. The photocatalytic behavior of the SnS₂-SiO₂@α-Fe₂O₃ nanocomposites was investigated by observing the degradation of methylene blue (MB). The results show an effective enhancement of photocatalytic activity for the degradation of MB especially for the 15 wt % SiO₂@α-Fe₂O₃ nanocomposites on SnS₂ flowers.
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