Hierarchically Porous Three-Dimensional (3D) Carbon Nanorod Networks with a High Content of FeNx Sites for Efficient Oxygen Reduction Reaction.

Efficient, durable, and inexpensive electrocatalysts are recommendable for accelerating the kinetics of oxygen reduction reaction and achieving high performance. Herein, with predesigned hierarchically porous silica nanorods as a hard template, hierarchically macro-bimodal meso/microporous 3D carbon interwoven nanorod networks containing a high content of single-atom FeNx species (Fe/RNC) were prepared by melting of precursors and confined pyrolysis within the pores of the hard template. What distinguishes the use of silica nanorods as a hard template is that it not only provides a porous texture for confined pyrolysis of the precursors but also the interwoven texture of the nanorods gives rise to a macroporous mesh-like morphology. Benefiting from the ultrahigh iron content (5.69 wt %) of the FeNx sites, a 3D porous network configuration with high accessibility of active centers, as well as a high specific surface area of 793 m 2 g -1 , the as-prepared Fe/RNC exhibited superior activity and durability for ORR and zinc-air batteries. For comparison, the catalyst Fe/NC-MCM, which was prepared with a similar procedure but with unimodal mesoporous silica MCM-41 nanoparticles as the hard template, possesses a less porous structure and active accessibility and thus exhibits inferior ORR activity. This work provides an effective design/nanoengineering for electrocatalysts in ORR and zinc-air batteries and will inspire more research on accessibility of active sites in non-noble carbon-based electrocatalysts.