Efficient Dienyl End-Capping of Ruthenium Catalyzed Ring Opening Metathesis Polymerization with Allyl Compounds through Base-Promoted Metallacyclobutane Decomposition.

Herein we demonstrate an effective and facile end-capping technique for ring-opening metathesis polymerization (ROMP) using readily available allyl compounds as a new type of terminating agents. This new type of end-capping reactions, which are based on the base-promoted decomposition of ruthenocyclobutane intermediates, introduce diene moiety onto the chain end of ROMP polymers while simultaneously deactivating the ruthenium complex. These termination reactions are highly efficient, typically completing within 1 minute at 0 °C with >95 % end-capping fidelity.