A Multiheteroatom [3,3]-Sigmatropic Rearrangement: Disproportionative Entries into 2-(N-Heteroaryl)methyl Phosphates and α-Keto Phosphates.
Yongkang YangChen QuXiao-Lan ChenKai SunLingbo QuWenzhu BiHao HuRui LiChunfeng JingDong-Hui WeiShengkai WeiYuanqiang SunHui LiuYu-Fen ZhaoPublished in: Organic letters (2018)
A novel multiheteroatom (N, O and P) [3,3]-sigmatropic rearrangement is disclosed, based on two important types of organophosphates, 2-(N-heteroaryl) methyl phosphates and α-keto phosphates, being accessed smoothly and efficiently.
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