Emergence of the Janus-MOF (J-MOF) Boat as a Nascent Amalgamation in the Arena of Photothermal Desalination.

The diminution of potable water is a pressing issue in several countries and is the most prioritized obligation of environmental scientists. Thence, the ardent emergence of photothermal interfacial evaporation (PTIE) is seen as a neoteric horizon in the avenue of water remediation. Consequently, for the first time, the decoration of metal-organic frameworks (MOFs) over a Janus architecture as an avant-garde marriage was explored in the domain of photothermal desalination. In this study, a solar absorber was developed by inducing phase change to Ni-doped HKUST-1 (Cu-MOF) via high-temperature calcination to create biphasic CuO/Cu 2 O caged in N-doped graphene oxide (NGO) sheets. The doping of Ni in the framework demonstrated to enhance the pyrrolic nitrogen (P N ) of NGO sheets, which improved the photothermal feature of the solar absorber in union with promoting Cu 2+ species as well as enriching the p-type nature of the biphasic configuration for augmented nonradiative relaxation of electrons. In order to take advantage of the robust potential of the designed solar absorber, it was coated over a Janus membrane prepared via the facile approach, composed of poly(methyl methacrylate) (PMMA) and agarose gel having opposing wettability, referred to as the J-MOF boat. This nascent amalgamation recorded a maximum evaporation rate of 1.5 kg/m 2 h with pure water and 1.3 kg/m 2 h with simulated seawater under 1 sun irradiation. This phenomenon was ascribed to the highly porous agarose layer to facilitate extraordinary water pumping, while concomitantly rejecting salts via capillary action in a nature-mimicking fashion as seen in mangrove trees. The boat-like feature arises from the PMMA layer to conduct PTIE at the water/air interface by uniformly dispersing the localized heat from the solar absorber owing to its low thermal conductivity and three-dimensional (3D) porous structure. Thus, it is believed that this nascent strategy could push the boundaries of solar-driven desalination.