Facilitated transport membrane with functionalized ionic liquid carriers for CO 2 /N 2 , CO 2 /O 2 , and CO 2 /air separations.

CO 2 separations from cabin air and the atmospheric air are challenged by the very low partial pressures of CO 2 . In this study, a facilitated transport membrane (FTM) is developed to separate CO 2 from air using functionalized ionic liquid (IL) and poly(ionic liquid) (PIL) carriers. A highly permeable bicontinuous structured poly(ethersulfone)/poly(ethylene terephthalate) ( b PES/PET) substrate is used to support the PIL-IL impregnated graphene oxide thin film. The CO 2 separation performance was tested under a mixture feed of CO 2 /N 2 /O 2 /H 2 O. Under 410 ppm of CO 2 at 1 atm feed gas, CO 2 permanence of 3923 GPU, and CO 2 /N 2 and CO 2 /O 2 selectivities of 1200 and 300, respectively, are achieved with helium sweeping on the permeate side. For increased transmembrane pressure (>0 atm), a thicker PIL-IL/GO layer was shown to provide mechanical strength and prevent leaching of the mobile carrier. CO 2 binding to the carriers, ion diffusivities, and the glass transition temperature of the PIL-IL gels were examined to determine the membrane composition and rationalize the superior separation performance obtained. This report represents the first FTM study with PIL-IL carriers for CO 2 separation from air.