Water-Soluble Pillar[n]arene Mediated Supramolecular Self-Assembly: Multi-Dimensional Morphology Controlled by Host Size.

We report tunable supramolecular self-assemblies formed by water-soluble pillar[n]arenes (WPns, n=5-7) and bipyridinium-azobenzene guests. Nanoscale or microscale morphology of self-assemblies in water was controlled by the host size of WPn. Supramolecular self-assemblies could undergo morphology conversion under irradiation with UV light.