Rational design of a flu-type heterometallic cluster-based Zr-MOF.

Yan-Xi TanXue YangBei-Bei LiDa-Qiang Yuan

Published in: Chemical communications (Cambridge, England) (2018)

Following the HSAB principle, the cooperative assembly of tetrahedral [Cu4I4(Ina)4]4- metalloligands and 8-connecting [Zr6(μ3-OH)8(OH)8]8+ building units leads to the first heterometallic cluster-based Zr-MOF (1). The results provide a successful strategy for rational design of heterometallic cluster-based Zr-MOFs.

Keyphrases

pet imaging
metal organic framework
positron emission tomography
pet ct