Substitution-pattern- and counteranion-dependent ion-pairing assemblies of heteroporphyrin-based π-electronic cations.
Masaki FujitaYohei HaketaShu SekiHiromitsu MaedaPublished in: Chemical communications (Cambridge, England) (2024)
Metal complexation and peripheral modifications of thiaporphyrins have been investigated for preparing polarized π-electronic cations with anion-dependent ion-pairing assembling modes, including charge-segregated structures exhibiting electric conductive properties.