Integrated photoelectrochemical energy storage cells prepared by benchtop ion soft landing.
Venkateshkumar PrabhakaranJoelle RomoAshish BhattaraiKyle GeorgeZachary M NorbergDavid KalbEdoardo ApraPeter A KottkeAndrei G FedorovPatrick Z El-KhouryGrant E JohnsonJulia LaskinPublished in: Chemical communications (Cambridge, England) (2022)
The exceptional photochromic and redox properties of polyoxometalate anions, PW 12 O 40 3- , have been exploited to develop an integrated photoelectrochemical energy storage cell for conversion and storage of solar energy. Elimination of strongly coordinating cations using benchtop ion soft landing leads to a ∼370% increase in the maximum power output of the device. Additionally, the photocathode displayed a pronounced color change from clear to blue upon irradiation, which warrants the potential application of the IPES cell in advanced smart windows and photochromic lenses.