Photoactive carbon monoxide-releasing coordination polymer particles.
Arnau Carné-SanchezShuya IkemuraReiko SakaguchiGavin A CraigShuhei FurukawaPublished in: Chemical communications (Cambridge, England) (2022)
We report the synthesis of photoactive carbon monoxide-releasing coordination polymer particles through the assembly of Mn(I) carbonyl complexes with bis(imidazole) ligands. The use of Mn(I) carbonyl complexes as metallic nodes in the coordination network avoids the potential for aggregation-induced self-quenching, favouring their use in the solid state.