Rotational spectroscopy of organophosphorous chemical agents: cresyl and phenyl saligenin phosphates.

Rizalina Tama Saragi Marcos Juanes Jose Luis Abad Alberto Lesarri Ruth Pinacho José Emiliano Rubio

Published in: Physical chemistry chemical physics : PCCP (2019)

Cresyl and phenyl saligenin phosphates have been probed in a jet expansion by broadband chirp-excitation microwave spectroscopy, revealing the most stable conformations and their structural properties. The rotational parameters offer a high-resolution univocal route for characterization of organophosphorous agents and a testbed for computational models.

Keyphrases

high resolution
high speed
single molecule
mass spectrometry
solid state
high frequency
molecular dynamics simulations
tandem mass spectrometry
radiofrequency ablation
energy transfer