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A wide pH-range stable crystalline framework based on the largest tin-oxysulfide cluster [Sn20O10S34].

Shan-Lin HuangLiang HeEr-Xia ChenHeng-Dong LaiJian ZhangQi-Pu Lin
Published in: Chemical communications (Cambridge, England) (2019)
We report, herein, a diamond-like oxysulfide framework, 3D-T4-SnOS, based on the largest supertetrahedral cluster of Sn4+ ions, i.e. [Sn20O10S34]. The framework remains intact in aqueous solution over a pH range between 1 and 14, and has a narrower optical bandgap, red-shifted fluorescence emission, and an enhanced photoelectric response compared to that of the smaller version, 2D-T3-SnOS, which has a building unit of supertetrahedral [Sn10O4S20].
Keyphrases
  • aqueous solution
  • high resolution
  • quantum dots
  • room temperature
  • mass spectrometry
  • high speed
  • ionic liquid