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Site-Selective Oxidative Coupling Reaction of Diamines toward Aminoazo Compounds.

Yuji LiuMingjie TangYuan LaiWei HuangYongxing Tang
Published in: Organic letters (2023)
A selective oxidative coupling reaction of a diamine containing both C - and N -NH 2 was achieved using acidic potassium permanganate as the coupling reagent. The reaction conditions were optimized, and the reaction selectivity was illustrated by quantum calculations. Furthermore, the azo-coupled product was derivatized to four nitroamine energetic materials with excellent detonation performances.
Keyphrases
  • room temperature
  • electron transfer
  • molecular dynamics
  • ionic liquid
  • molecular dynamics simulations
  • monte carlo