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Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B12H11NH₃].

Yuanbin ZhangYuji SunTao WangJiyong LiuBernhard SpinglerSimon Duttwyler
Published in: Molecules (Basel, Switzerland) (2018)
The synthesis and structural characterization of new derivatives of [B12H12]2- is of fundamental interest and is expected to allow for extended applications. Herein we report on the synthesis of a series of amidine, amide, urea and isocyanate derivatives based on the amino-closo-dodecaborate anion [B12H11NH₃]-. Their structures have been confirmed by spectroscopic methods, and nine crystal structures are presented.
Keyphrases
  • ionic liquid
  • room temperature
  • structure activity relationship
  • high resolution