Nanocellulose-Based Hybrid Materials for UV Blocking and Mechanically Robust Barriers.
Tiffany AbitbolAnwar AhniyazRubén Álvarez-AsencioAndreas FallAgne SwerinPublished in: ACS applied bio materials (2020)
Nanocellulose (NC)-based hybrid coatings and films containing CeO 2 and SiO 2 nanoparticles (NPs) to impart UV screening and hardness properties, respectively, were prepared by solvent casting. The NC film-forming component (75 wt % of the overall solids) was composed entirely of cellulose nanocrystals (CNCs) or of CNCs combined with cellulose nanofibrils (CNFs). Zeta potential measurements indicated that the four NP types (CNC, CNF, CeO 2 , and SiO 2 ) were stably dispersed in water and negatively charged at pH values between 6 and 9. The combination of NPs within this pH range ensured uniform formulations and homogeneous coatings and films, which blocked UV light, the extent of which depended on film thickness and CeO 2 NP content, while maintaining good transparency in the visible spectrum (∼80%). The addition of a low amount of CNFs (1%) reduced the film hardness, but this effect was compensated by the addition of SiO 2 NPs. Chiral nematic self-assembly was observed in the mixed NC film; however, this ordering was disrupted by the addition of the oxide NPs. The roughness of the hybrid coatings was reduced by the inclusion of oxide NPs into the NC matrix perhaps because the spherical oxide NPs were able to pack into the spaces between cellulose fibrils. We envision these hybrid coatings and films in barrier applications, photovoltaics, cosmetic formulations, such as sunscreens, and for the care and maintenance of wood and glass surfaces, or other surfaces that require a smooth, hard, and transparent finish and protection from UV damage.
Keyphrases
- room temperature
- ionic liquid
- oxide nanoparticles
- aqueous solution
- reduced graphene oxide
- healthcare
- palliative care
- oxidative stress
- pseudomonas aeruginosa
- quality improvement
- biofilm formation
- carbon nanotubes
- magnetic nanoparticles
- climate change
- optical coherence tomography
- staphylococcus aureus
- resting state
- functional connectivity
- human health