Polyvinyl alcohol/sodium alginate-based conductive hydrogels with in situ formed bimetallic zeolitic imidazolate frameworks towards soft electronics.

Bimetallic zeolitic imidazolate frameworks (BZIFs) have received enormous attention due to their unique physi-chemical properties, but are rarely reported for electrically conductive hydrogel (ECH) applications arising from low intrinsic conductivity and poor dispersion. Herein, we propose an innovative strategy to prepare highly conductive and mechanically robust ECHs by in situ growing Ni/Co-BZIFs within the polyvinyl alcohol/sodium alginate dual network (PZPS). 2-methylimidazole (MeIM) ligands copolymerize with pyrrole monomers, enhancing the electrical conductivity; meanwhile, MeIM ligands act as anchor points for in-situ formation of BZIFs, effectively avoiding phase-to-phase interfacial resistance and ensuring a uniform distribution in the hydrogel network. Due to the synergism of Ni/Co-BZIFs, the PZPS hydrogel exhibits a high areal capacitance of 630.3 mF·cm -2 at a current density of 0.5 mA·cm -2 , promising for flexible energy storage devices. In addition, PZPS shows excellent mechanical strength and toughness (with an ultimate tensile strength of 405.0 kPa and a toughness of 784.2 kJ·m -3 at an elongation at break of 474.0 %), a high gauge factor of up to 4.18 over an extremely wide stress range of 0-42 kPa when used as flexible wearable strain/pressure sensors. This study provides new insights to incorporating highly conductive and uniformly dispersed ZIFs into hydrogels for flexible wearable electronics.