Facile Fabrication of Semiconducting Single-Walled Carbon Nanotubes Patterns on Flexible Substrate Based on a Photoimmobilization Technique.

Single-walled carbon nanotubes (SWCNTs) have attracted significant attention due to their outstanding properties. For their wide applications in electronics and optoelectronics, pure semiconducting SWCNTs (s-SWCNTs) and their precise placement are preconditions. Recent advances have focused on developing effective strategies to separate s-SWCNTs from raw SWCNTs, a mixture of metallic and semiconducting nanotubes, and deposit s-SWCNTs on target substrates. Herein, a polyfluorene-based alternative copolymer (PFBP) containing the benzophenone group was employed. PFBP achieved higher yield for s-SWCNTs than the well-studied poly(9,9-dioctylfluorene) through solution process. Subsequently, the dispersed s-SWCNTs were immobilized on a flexible polyethylene terephthalate in a facile manner by the photoreactive benzophenone group upon exposure to UV irradiation, and chemically robust patterns were fabricated from micro to macro scales through photomasks. Our method accomplished by utilizing photoimmobilization is a simple cleaning procedure and an important step forward in pitch scaling for further applications of conjugated polymer wrapped s-SWCNTs.