The Influence of the Thickness of Compact TiO2 Electron Transport Layer on the Performance of Planar CH3NH3PbI3 Perovskite Solar Cells.
Andrzej SławekZbigniew StarowiczMarek LipińskiPublished in: Materials (Basel, Switzerland) (2021)
In recent years, lead halide perovskites have attracted considerable attention from the scientific community due to their exceptional properties and fast-growing enhancement for solar energy harvesting efficiency. One of the fundamental aspects of the architecture of perovskite-based solar cells (PSCs) is the electron transport layer (ETL), which also acts as a barrier for holes. In this work, the influence of compact TiO2 ETL on the performance of planar heterojunction solar cells based on CH3NH3PbI3 perovskite was investigated. ETLs were deposited on fluorine-doped tin oxide (FTO) substrates from a titanium diisopropoxide bis(acetylacetonate) precursor solution using the spin-coating method with changing precursor concentration and centrifugation speed. It was found that the thickness and continuity of ETLs, investigated between 0 and 124 nm, strongly affect the photovoltaic performance of PSCs, in particular short-circuit current density (JSC). Optical and topographic properties of the compact TiO2 layers were investigated as well.
Keyphrases
- solar cells
- perovskite solar cells
- quantum dots
- visible light
- room temperature
- atomic force microscopy
- high speed
- optical coherence tomography
- low cost
- ionic liquid
- healthcare
- energy transfer
- photodynamic therapy
- mental health
- working memory
- single molecule
- positron emission tomography
- density functional theory
- pet imaging
- mass spectrometry
- molecular dynamics