Metal Ions as the Third Component Coordinate with the Guest to Stereoscopically Enhance the Phosphorescence Properties of Doped Materials.

The construction of multicomponent doped systems is an important direction for the development of phosphorescence materials. Herein, benzophenone is selected as the host, phenylquinoline isomers are designed as guests, and seven metal ions are selected as the third component (Al 3+ , Cu +/2+ , Zn 2+ , Ga 3+ , Ag + , Cd 2+ , and In 3+ ) to construct the three-component doped system. Ag + and Cd 2+ can considerably increase the emission intensity up to 38 times, and the highest phosphorescence quantum efficiency reaches 70%. Al 3+ , Ga 3+ , and In 3+ can prolong the emission wavelength, and the phosphorescence wavelength can be red-shifted up to 60 nm. Cu 2+ , Ga 3+ , and In 3+ can extend the phosphorescence lifetime by a maximum of 3.6 times. A series of experiments demonstrated that the coordination of metals and guests is the key to improve the phosphorescence properties. This work presents a simple and effective strategy to enhance the phosphorescence properties of doped materials.