Janus Photochemical/Photothermal Azobenzene Inverse Opal Actuator with Shape Self-Recovery toward Sophisticated Motion.

Azobenzene actuators have aroused enormous research interest due to their excellent performance and promising applications in the fields of soft robots, artificial muscles, etc. However, there are still challenges for the fabrication of azobenzene actuators with a sophisticated actuation mode owing to the unitary actuation direction and slow thermal relaxation of cis - to trans -azobenzene mesogens. To solve these problems, this paper presents a facile fabrication method of a Janus azobenzene inverse opal actuator with one side made of the monodomain azobenzene polymer and the other side made of the polydomain azobenzene inverse opal structure. Gradient-layer spacing structure of the film in its cross section is proven by synchrotron small-angle X-ray diffraction. The introduction of the inverse opal structure mainly provides a polydomain mesogen alignment, large specific surface area, low elastic modulus, and structure color. The synergetic actuation of the photochemical/photothermal mode produces multiple actuation directions, a larger actuation force, and an alteration of the structure color. Shape self-recovery of this Janus azobenzene actuator contributes to some promising applications, such as crawling on a smooth surface, driving an engine axis, and logic electric circuit for the coding technique. This work is of great significance for the design and fabrication of novel-type photoactuators.