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Evaporation rate-based selection of supramolecular chirality.

Shingo HattoriStefaan VandendriesscheGuy KoeckelberghsThierry VerbiestKazuyuki Ishii
Published in: Chemical communications (Cambridge, England) (2018)
We demonstrate the evaporation rate-based selection of supramolecular chirality for the first time. P-type aggregates prepared by fast evaporation, and M-type aggregates prepared by slow evaporation are kinetic and thermodynamic products under dynamic reaction conditions, respectively. These findings provide a novel solution reaction chemistry under the dynamic reaction conditions.
Keyphrases
  • electron transfer
  • energy transfer
  • solid state
  • aqueous solution