Evaporation rate-based selection of supramolecular chirality.
Shingo HattoriStefaan VandendriesscheGuy KoeckelberghsThierry VerbiestKazuyuki IshiiPublished in: Chemical communications (Cambridge, England) (2018)
We demonstrate the evaporation rate-based selection of supramolecular chirality for the first time. P-type aggregates prepared by fast evaporation, and M-type aggregates prepared by slow evaporation are kinetic and thermodynamic products under dynamic reaction conditions, respectively. These findings provide a novel solution reaction chemistry under the dynamic reaction conditions.