Tuning the electronic properties of Zr UiO-66 through defect-functionalised multivariate modulation.
Carmen Rosales-MartínezMarcelo AssisCelia Castillo-BlasIsabel Abánades LázaroPublished in: Chemical communications (Cambridge, England) (2024)
The multivariate modulation of Metal-Organic Frameworks is presented as a valuable tool to introduce multiple functional units into UiO-66 while increasing its porosity. This manuscript encloses a comprehensive study using p -functionalised benzoate -NO 2 , -SO 3 and -SH modulators, rationalizing the defects introduced and their impact on properties.