Determining the Energy Gap between the S 1 and T 1 States of Thermally Activated Delayed Fluorescence Molecular Systems Using Transient Fluorescence Spectroscopy.

The energy gap (Δ E S-T ) between the lowest single and triple excited states is a crucial parameter for thermally activated delayed fluorescence (TADF) molecular systems with high quantum yield. However, a reliable experimental approach to precisely determine this value is challenging. Here, we introduce a new, simple, and efficient strategy to accurately obtain the Δ E S-T in TADF systems from time-resolved fluorescence spectroscopy using a recently reported TADF molecule, DMACPDO, as a representative. By introducing an explicit model to describe the corresponding singlet-triplet coupling system, elusive intersystem crossing and reverse intersystem crossing rates can be extracted by fitting the kinetics of the observed fluorescence. The Δ E S-T value can then be determined. Moreover, our modeling accurately explained the opposite trend in fluorescence intensity of DMACPDO with solvent polarity under air-saturated and deoxygenated conditions. Additionally, the validity of this approach has been demonstrated in another well-known TADF molecule, 4CzIPN. We demonstrate how this approach of determining Δ E S-T sheds light on a deeper understanding of energy-loss mechanisms involved in related photoconversion processes.