P2-Type Moisture-Stable and High-Voltage-Tolerable Cathodes for High-Energy and Long-Life Sodium-Ion Batteries.

P2-Na 0.67 Ni 0.33 Mn 0.67 O 2 represents a promising cathode for Na-ion batteries, but it suffers from severe structural degradation upon storing in a humid atmosphere and cycling at a high cutoff voltage. Here we propose an in situ construction to achieve simultaneous material synthesis and Mg/Sn cosubstitution of Na 0.67 Ni 0.33 Mn 0.67 O 2 via one-pot solid-state sintering. The materials exhibit superior structural reversibility and moisture insensitivity. In-operando XRD reveals an essential correlation between cycling stability and phase reversibility, whereas Mg substitution suppressed the P2-O2 phase transition by forming a new Z phase, and Mg/Sn cosubstitution enhanced the P2-Z transition reversibility benefiting from strong Sn-O bonds. DFT calculations disclosed high chemical tolerance to moisture, as the adsorption energy to H 2 O was lower than that of the pure Na 0.67 Ni 0.33 Mn 0.67 O 2 . A representative Na 0.67 Ni 0.23 Mg 0.1 Mn 0.65 Sn 0.02 O 2 cathode exhibits high reversible capacities of 123 mAh g -1 (10 mA g -1 ), 110 mAh g -1 (200 mA g -1 ), and 100 mAh g -1 (500 mA g -1 ) and a high capacity retention of 80% (500 mA g -1 , 500 cycles).