Metal Microfibers Delivered Eddy Current Heating for Efficient Synthesis and Regeneration of Metal-Organic Framework Monoliths.

On the basis of stainless-steel fiber (SSF)-delivered localized Eddy current heating (LECH) in response to an alternating magnetic field, a novel LECH-driven framework synthesis (LIFS) strategy has been developed for highly efficient metal-organic framework (MOF) synthesis, resulting in the production of a set of SSF/MOF composites consisting of MOF-coated SSF (SSF@MOF) fibers and free MOF crystals. Detailed studies on the LIFS reaction kinetics indicate that the use of LIFS can greatly promote MOF production in comparison to the conventional solvothermal reactions. To facilitate the practical applications, the resulting powder SSF/UiO-66-NH2 composites, as a typical example, are further processed into well-shaped SSF/UiO-66-NH2 monoliths (SUS) with varied MOF loadings. In SUSs, the embedded SSFs exhibit well-controlled LECH capacities depending on the applied magnetic field strength. Driven by LECH, SUS monoliths can be uniformly heated and fully regenerated, demonstrating a LECH-triggered framework regeneration (LIFR) process for highly efficient regenerating MOF monoliths. As LECH is delivered by the low-cost commercial SSFs and remotely triggered by an external magnetic field, our currently developed LIFS and LIFR processes provide a novel, low-cost, and energy-efficient way to highly efficiently synthesize and regenerate MOF materials.