Grave-to-cradle photothermal upcycling of waste polyesters over spent LiCoO 2 .
Xiangxi LouPenglei YanBinglei JiaoQingye LiPanpan XuLei WangLiang ZhangMuhan CaoGuiling WangZheng ChenQiao ZhangJinxing ChenPublished in: Nature communications (2024)
Lithium-ion batteries (LIBs) and plastics are pivotal components of modern society; nevertheless, their escalating production poses formidable challenges to resource sustainability and ecosystem integrity. Here, we showcase the transformation of spent lithium cobalt oxide (LCO) cathodes into photothermal catalysts capable of catalyzing the upcycling of diverse waste polyesters into high-value monomers. The distinctive Li deficiency in spent LCO induces a contraction in the Co-O 6 unit cell, boosting the monomer yield exceeding that of pristine LCO by a factor of 10.24. A comprehensive life-cycle assessment underscores the economic viability of utilizing spent LCO as a photothermal catalyst, yielding returns of 129.6 $·kg LCO -1 , surpassing traditional battery recycling returns (13-17 $·kg LCO -1 ). Solar-driven recycling 100,000 tons of PET can reduce 3.459 × 10 11 kJ of electric energy and decrease 38,716 tons of greenhouse gas emissions. This work unveils a sustainable solution for the management of spent LIBs and plastics.
Keyphrases
- life cycle
- photodynamic therapy
- cancer therapy
- drug delivery
- drug release
- solid state
- highly efficient
- single cell
- climate change
- municipal solid waste
- reduced graphene oxide
- heavy metals
- metal organic framework
- ion batteries
- room temperature
- gold nanoparticles
- human health
- bone marrow
- simultaneous determination
- tandem mass spectrometry